Yeah,we once post a article about free MCTS 70-536/70-528 online resources to help the candidates for .Net 2.0 or .net 3.5 certs out .However, we think it is not enough to follow those recommendations about the preparation guide or practice tests. The best materials should be from MSDN documentation, more important, which is free and can clear your confusion about 70-536 MS press self –paced training kit or other books.
So, we do a lot of diggings in MSDN 。Hope it useful for you, guys.

70-536 C# notes :
Free explanation to 70-536 main topic area :

Implementing service processes, threading, and application domains in a .NET Framework application

Create a unit of isolation for common language runtime within a .NET Framework application by using application domains

Embedding configuration, diagnostic, management, and installation features into a .NET Framework application (14 percent)

Improving the security of .NET Framework applications by using the .NET Framework security features (20 percent)

Implementing serialization and input/output functionality in a .NET Framework application (18 percent)

Implementing interoperability, reflection, and mailing functionality in a .NET Framework application (11 percent)

Implementing globalization, drawing, and text manipulation functionality in a .NET Framework application (11 percent)

70-536 VB notes:

MSDN documentation

How to create a custom culture?

How to use GzipStream class to compress a file?

How to set Option Explicit / Option Strict / Option Compare in the IDE?

How to set the Lib Path in the Visual Studio Integrated Development Environment?

What is a component?

How to use the DeflateStream class to compress a file?

How to set the Lib Path in the Visual Studio Integrated Development Environment?

What is Cryptosystem?

What are the differences between the SortedList and SortedDictionary generic classes?

What is a runtime host?

 

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